关于压氢还原金属氨配合物时最佳配位数的论证

A Certification of Optimal Ligancy of M(NH_3)_m^(n) Reduced by Pressure Hydrogen to Metal Form

本文通过理论计算证明,压氢还原金属氨配合物M(NH_3)_m^n+的最佳配位数等于其金属离子M^(n+)的氧化数(即m=n),此时还原反应的标准电动势或平衡常数最大。

This paper certifies with theoretical calculation that the ligancy of metal amine complex(M(NH_3)_m^(n+)) equivallent to oxidation number of metal-ion (M^(n+)), i、e、m=n, is optimum in processing of reduction of M(NH_3)_m^(n+) by pressure hydrogen to metal form, and that electromotive force or equilibrium constant of above reduction reaction is maximum.