摘要
本文通过电环化反出实例,应用前线轨道理论清楚地解释了该反应中的高度立体选择性问题。阐述了前线分子轨道对探讨有机反应机理和预测产物构型的重要作用。
Using the theory of frontier molecular orbits, this article explains clearly stereoselectivity through the examples of electrocyclic reactions. It also represents the important role by FMO in investigating mechanism of organic reactions and determining preriously configuration of products.
关键词
前线分子轨道
电环化反应
选择性
Frontier Molecular Orbit
Electrocyclization
Stereoselectivity
