摘要
通过固相合成技术制备前过渡元素金属原子簇是一个富有吸引力的研究领域。本文简要地介绍了这一合成技术的特点,并对一些典型的原子簇(主要是含有M_6簇单元)的结构、相互连接类型以及通过共享金属原子的缩聚形式从广泛的角度进行了阐述。
It is an attractive research field for chemists that clusters of early transition elements are prepared by the method of solid state synthesis. The characteristics of this technique are introduced briefly. Clusters of these valence electron poor metals, mainly with the M6units, their different types of interconnections, and their condensation via shared metal atoms, are described from a rather general point of view.
