摘要
封闭型硼烷和对应的多面体碳烷的骨架多面体,互为共轭多面体。本文在讨论它们的化学键性质的基础上,将一般的原子簇化合物,按骨架多面体的顶点数和面数的相对大小,进行分类。然后,逐类地建议了相应的拓朴结构规则,用于讨论各类原子簇化合物的电子构型。
In this paper the polyhedral clusters have been classified into three categories according to the dif ference between the numoer of vertex n and the number of face f in each skeleton to be larger, smaller and equal to zero. The corresponding structural rules have also been suggested to discuss the electronic configurations of each kind of clusters.
基金
国家自然科学基金
