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生物质催化气化制取富氢燃气的研究 被引量:12

Potential of hydrogen production from biomass catalytic gasification
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摘要 以流化床为反应器 ,探讨了一些主要参数如 :反应器温度 ,水蒸气 ,当量比ER以及催化剂对气体成分、氢产率和潜在氢产率的影响。实验所用催化剂为白云石和镍基催化剂。在实验条件范围内 ,氢产率为 2 2— 83g/kg生物质 (湿基 ) ,潜在氢产率为 115— 2 2 3g/kg生物质 (湿基 )。结果表明 ,较高的反应器温度 ,适当的水蒸气添加量可以有效提高氢的产出 ;白云石和镍基催化剂可使产品气中的氢含量提高 10 %以上。 Parametric experiments were performed in a fluidized bed to determine the effects of reaction temperature, steam, equivalence ratio (ER) and catalysts on gas composition, hydrogen and potential hydrogen yield. The catalysts used were dolomites and nickel based catalysts and were located in gasifier and a downstream fixed reactor, respectively. Of the conditions tested, hydrogen yield ranges between 22 and 83 g per kg of biomass (wet basis) and hydrogen yield potential ranges between 115 and 223 g per kg of biomass (wet basis). The experimental results prove that higher reaction temperature, proper steam quantity and ER will contribute to more hydrogen production. Hydrogen concentration of gaseous product can be increased over 10% through the use of dolomite and nickel based catalysts.
出处 《环境污染治理技术与设备》 CSCD 北大核心 2003年第11期31-34,共4页 Techniques and Equipment for Environmental Pollution Control
基金 国家自然科学基金资助项目 ( 2 0 2 0 60 3 1) 2 0 0 1年度中国科学院百人计划资助项目
关键词 催化气化 生物质 白云石 镍基催化剂 硫化床 富氢燃气 biomass catalytic gasification hydrogen production
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参考文献17

  • 1Cox J L, Tonkovich A Y, Elliott D C, et al. Second Biomass Conference of the Americans : Energy, Environment,Agriculture, and Industry Proceedings, Portland, Oregon, August 21--24,1995.657--674.
  • 2Mann M K. Technical and economic assessment of producing hydrogen by reforming syngas from the battelle indirectly heated biomass gasifier. National Renewable Energy Laboratory Report No. NREL/TP-431-8143,1995.
  • 3Corella J, Aznar M P, Delgado J, Aldea E. Steam gasification of cellulosic wastes in a fluidized bed with downsteam vessels. Ind Eng Chem Res , 1991,30:2252--2262.
  • 4Herguido J , Corella J, Gonzales-Saiz J. Steam gasification of lignocellulosic residues in a fluidized bed at a small pilot scale:Effect of the type of feedstock. Ind Eng Chem Res, 1992,31 : 1274--1282.
  • 5Aznar M P, Corella J, Delgado J, Lahoz J. Improved steam gasification of lignocellulosic residues in a fluidized bed with commercial steam reforming catalysts. Ind Eng Chem Res, 1993, 32:1--10.
  • 6Wang Y, Kinoshita C M. Experimental analysis of biomass gasification with steam and oxygen. Solar Energy, 1992, 49(3) : 153--158.
  • 7Kinoshita C M, Wang Y, Zhou J. Effect of reformer conditions on catalytic reforming of biomass-gasification tars. Ind Eng Chem Res, 1995, 34:2949--2954.
  • 8Narváez I, Orio A, Aznar M P, Corella J. Biomass gasification with air in an atmospheric bubbling fluidized bed: Ef-fet of six operational variables on the quality of the produced raw gas. Ind Eng Chem Res, 1996, 35:2110--2120.
  • 9Delgado J, Aznar M P, Corella J. Calcined dolomite, magnesite and calcite for cleaning hot gas from a fluidized bed biomass gasifier with steam: Life and usefulness. Ind Eng Chem Res, 1996, 35 : 3637--3643.
  • 10Delgado J, Aznar M P. Biomass gasification with steam in fluidized bed: Effectiveness of CaO, MgO, and CaO-MgO for hot raw gas cleaning. Ind Eng Chem Res, 1997, 36:1535--1543.

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