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Effect of Rare Earth Elements on Exchange Performances of Cesium Ion-Sieve

Effect of Rare Earth Elements on Exchange Performances of Cesium Ion-Sieve
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摘要 The exchange performances and the distribution coefficient of Cesium Ion-Sieve (Cs-IS) for cesium and for some rare earth elements were compared. In particula r, the effects of neodymium on the cesium ion exchange and the Cs+ selectivity v ariation on Cs-IS owing to introduction of rare earth elements into HLLW were s tudied. Though rare earth elements exhibit a small influence on the distributio n coefficient for Cs+, they impair Cs-exchange capacity of Cs-IS to some ext ent. This interruption on the selectivity to Cs+ can be significantly eliminat ed provided an appropriate ratio of liquid to solid V:m is used. The exchange performances and the distribution coefficient of Cesium Ion-Sieve (Cs-IS) for cesium and for some rare earth elements were compared. In particula r, the effects of neodymium on the cesium ion exchange and the Cs+ selectivity v ariation on Cs-IS owing to introduction of rare earth elements into HLLW were s tudied. Though rare earth elements exhibit a small influence on the distributio n coefficient for Cs+, they impair Cs-exchange capacity of Cs-IS to some ext ent. This interruption on the selectivity to Cs+ can be significantly eliminat ed provided an appropriate ratio of liquid to solid V:m is used.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2003年第1期42-45,共4页 稀土学报(英文版)
基金 ProjectsupportedbytheNationalAdvancedMaterialsCommitteeofChina ( 2 99710 2 2 ) ,theNationalNaturalScienceFounda tionofChina ( 86 3 715 0 0 4-2 2 0 )andtheDoctoralProgramFoundationoftheMinistryofEducationofChina ( 970 0 5 6 19)
关键词 chemical separating engineering high-level radioactive liquid waste cesium io n-sieve inorganic ion exchange rare earths chemical separating engineering high-level radioactive liquid waste cesium io n-sieve inorganic ion exchange rare earths
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  • 1P. K. Sinha,P. M. Satyasai,R. Shankar,R. Muthiah,S. Bera,S. V. Narasimhan,A. N. Pandey,A. Jaleel.Removal of137Cs from an intermediate level liquid waste by using various ion-exchange media[J].Journal of Radioanalytical and Nuclear Chemistry.1999(2)
  • 2M. Grunder,J. F. Dozol,Z. Asfari,J. Vicens.Simultaneous removal of technetium and cesium by functionalized calixarenes from acidic liquid waste[J].Journal of Radioanalytical and Nuclear Chemistry.1999(1)

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