期刊文献+

过氧化物预硫化天然胶乳硫化过程胶乳胶膜的热分析 被引量:1

THERMAL ANALYSIS OF PEROXIDE PREVULCANIZED NATURAL RUBBER LATEX FILM IN THE PROCESS OF VULCANIZATION
下载PDF
导出
摘要 用热重法-微商热重法(TG-DTG)和差热分祈(DTA)研究了用过氧化物预硫化胶乳过程中,硫化时间不同时胶乳胶膜热氧降解的过程。结果表明,过氧化物预硫化胶乳胶膜的起始降解温度、DTG峰顶温度和DTG峰的终止温度、起始放热温度和DTA峰顶温度均随硫化过程发生变化。 The process of change for thermo-oxidative degradation of latex film at different vulcanization time during the prevulcanization of latex by peroxide was studied by using of TG-DTG and DTA. The results show that initial degradation temperature of PPVL film, the top temperature of DTG peak and the temination temperature of DTG peak, as well as the initial exothemal temperature and the top temperature of DTA peak change along with the vulcanization process.
出处 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2003年第6期191-193,共3页 Polymer Materials Science & Engineering
基金 中国热带农业科学院基金资助项目
关键词 过氧化物 预硫化 天然胶乳 硫化过程 胶膜 热分析 natural rubber latex prevulcanized latex peroxide prevulcanized natural rubber latex thermal analysis
  • 相关文献

参考文献1

  • 1ZHANGBei-long LIUHui-lun.热带作物学报(Chinese Journall of Tropical Crops),2001,22(2):1-7.

同被引文献13

  • 1敖宁建,陈美,周惠玲,钱红莲.蒙脱土对医用天然胶乳制品的结构和热稳定性影响[J].电子显微学报,2003,22(6):510-511. 被引量:2
  • 2陈美 张北龙.FTIR研究过氧化物预硫化胶乳胶膜热老化[J].功能材料,2001,32:1345-1345.
  • 3Gregg E C,Katrenick S E. Chemical structure in Cri-1 ,4-polybutadiene vulcanzates model compound approach [ J ].Rubber Chem Technol, 1970,43:549 - 571.
  • 4Loan L D. Mechanism of peroxide vulcanization of Elastomers[ J ]. Rubber Chem Technol, 1967,40 : 149 - 176.
  • 5SAID Ma'zam M D, Pendle T D, Blaekley D C. Peroxide prevuleanization of natural rubber latex [ J ]. J Nat Rubber Res, 1990,5 (1):27-40.
  • 6Zhang Bei-long,Chen Mei,Ao Ning-jian. Study on hot air aging and thermooxidafive degradation of peroxide prevulcanized natural robber latex film[J]. Appl Polym Sci,2004,92(5) :3196 - 3200.
  • 7SAID Ma'zam M D,Pendle T D, Blackley D C. Kinetics of decomposition of tert-butyl peroxyisobutyrate during vulcanization of rubber latex[J] .J Nat Rubber Res, 1991, 6(3) :158- 171.
  • 8Coats A W, Redfern J P. Kinetic parameters from thermogravivimetric data[ J ]. Nature, 1964, 201 : 68 - 69.
  • 9Chen Mei, Ao Ning-jian, Zhang Bei-long. Comparison and evaluation of the thermooxidative stability of medical natural rubber latex products prepared with a sulfur vulcanization system and a peroxide vulcanization system[J]. Appl Polym Sci, 2005,98(2) :591 - 597.
  • 10Morand. J L. Oxidation of Polyisoprene [ J ]. Rubber Chem Technol, 1974,47(5) : 1094 - 1099.

引证文献1

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部