摘要
Suspension catalytic distillation (SCD) has been developed recently as an innovative technology in catalytic distillation. In this paper, a brief introduction to SCD is given and an equilibrium stage (EQ) model is developed to simulate this new process for synthesis of linear alkylbenzene (LAB) from benzene and 1-dodecene.Since non-ideality of this reaction system is not strong, EQ model developed could be applied to it successfully.Simulation results agree well with experimental data, and indicate some characteristics of SCD process as an advanced technology for the production of LAB: 100% conversion of olefins, low temperature (90-100℃) and low benzene/olefin mole ratio.
Suspension catalytic distillation (SCD) has been developed recently as an innovative technology in catalytic distillation. In this paper, a brief introduction to SCD is given and an equilibrium stage (EQ) modei is developed to simulate this new process for synthesis of linear alkylbenzene (LAB) from benzene and 1-dodecene. Since non-ideality of this reaction systern is not strong, EQ modei developed could be applied to it successfully. Simulation results agree well with experimental data, and indicate some characteristics of SCD process as an advanced technology for the production of LAB: 100% conversion of olefins, low temperature (90-100℃) and low benzene/olefin mole ratio.
基金
Major State Basic Research Development Program(No.G2000048006)
