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氮杂芳基三脚架配体及其金属超分子化合物 被引量：2

Heteroaryl Tripodal Ligands and their Metallosupramolecular Complexes
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摘要 氮杂芳基三脚架配体可分为柔性和刚性两种 ,它们均有三个或三个以上的配位点 ,配体中配位点数目和位置的改变都会对金属超分子配合物的结构产生很大的影响。本文简单介绍了氮杂芳基三脚架配体自组装的特点及其所生成的超分子化合物的主要结构类型。 Heteroaryl tripodal ligands can be classified as flexible and rigid with three or more donor atoms.The number and location of the donors in the ligand influence greatly the supramolecular structures of the coordination complexes formed.Some of the major structural and self-assembly characteristics will be presented.
作者 谭海燕 张华新 康北笙
机构地区 中山大学化学与化学工程学院 中国科学院上海有机化学研究所金属有机化学国家重点实验室上海
出处 《化学通报》 CAS CSCD 北大核心 2003年第11期755-761,共7页 Chemistry
基金 国家自然科学基金 (2 99730 5 9) 广东省自然科学基金 (0 0 12 32 ) 高等学校博士学科点专项科研资金资助项目
关键词 氮杂芳基三脚架配体 金属 超分子化合物 自组装 结构类型 Heteroaryl tripodal ligand, Metallosupramolecule, Self-assembly
分类号 O641.4 [理学—物理化学]
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参考文献10

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同被引文献13

  • 1Philip Lightfoot, Alan Snedden. Metal-organic co-ordination frameworks based on mixed N - and O - donor ligands : Crystal structures of { Co ( phth ) S2 ( bipy ) ] and [ Co2 (real) 2 ( bipy ) ( H2O ) 2 ] ( phth = Phthalate,mal = malonate, bipy = 4,4'-bipyridine) [ J]. J Chem Soc, Dalton Trans, 1999, (20) : 3549 - 3551.
  • 2Gang Wu, Xiao-Feng Wang, Taka-akiOkamura, et al. Syntheses, structures, and photoluminescence propertiesof metal ( Ⅱ ) halide complexes with pyridine-containing flexible tripodal ligands[ J]. Inorg Chem,2006, (45) :8523 - 8532.
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  • 5Burrows, A. D. , Mingos, D. M. P. , While, A. J. P. , et al. Crystal engineering of metal complexes based on chargeaugmented double hydrogen-bond interactions between thiosemicarbazides and carboxylates [ J ]. Chem. Commun. ,1996,97-99.
  • 6Desiraju, G. R. Designer crystals: intermolecular interactions, network structuresand supramolecular synthons [ J ]. Chem. Commun. , 1997,1475-1482.
  • 7Philip Lightfoot and Alan Snedden. Metal-organic coordination frameworks Based on mixed N-and O-donor ligands : crystal structures of [ Co ( phth ) 2 ( bipy ) ] and [ Co2 ( mal)2 (bipy) ( H2O)2 ] ( phth = Phthalate, real = malonate, bipy = 4, 4 '-bipyridine ) [ J ]. J. Chem. Soc. , Dalton Trans. , 1999, (20) :3549-3551.
  • 8Gang Wu, Xiao-Feng Wang, Taka-akiOkamura, et al. Syntheses, structures, and photoluminescence properties of metal (Ⅱ)halide complexes with pyridine-containing flexible tripodal ligands [ J ]. Inorg. Chem. , 2006,45 : 8523-8532.
  • 9Bell, I. M. , Erb, J. M. , Freidinger, R. M, et al. Development of orally active oxytocin antagonists:studies on 1-( 1-{4-[ 1-( 2-methyl-1-oxidopyridin-5-ylmethyl ) piperidin-4-yloxy ]-2- methoxybenzoyl t piperi din-4-yl)-1, 4-dihydrobenz[ d ] [ 1,3 ] oxazin-2-one ( L-372,662 ) and related pyridines [ J ]. J. Med. Chem. , 1998,41 ( 12 ) : 2146-2163.
  • 10陈芬儿.有机药物合成法[M].北京:中国医药科技出版社,1999.

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化学通报
2003年 第11期

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