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哌嗪氨基二硫代甲酸型螯合树脂的合成及其吸附性能 被引量:2

SYNTHESIS AND SORPTION PROPERTIES OF NEW CHELATING RESINS OF DITHIOCARBAMIC ACID TYPE CONSISTING A PIPERAZINE BACKBONE
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摘要 用哌嗪和二硫化碳反应合成氨基二硫代甲酸中间体 ,再与二卤代烃反应得到 1 4 双 (二硫代酯基 )哌嗪聚合物 ,考察了中间体和螯合树脂对Ag+,Cu2 +,Zn2 +,Ni2 +,Co2 +,Pb2 +,Pd2 +,Cr3+的静态吸附性能 .结果表明 ,两者均可以吸附金属离子 ,缩聚后的螯合树脂具有更强的吸附能力 . Two sorbents(Pzdtc,Resin)were synthesized by the reaction between di(alkyldithioate)piperazine and dichloroethane repspectively.The sorption and selectivity properties of two sorbents for Ag +,Cu 2+ ,Zn 2+ ,Cd 2+ ,Co 2+ ,Ni 2+ ,Pb 2+ ,Pd 2+ were also determined.In general,the two sorbents have high sorption capacities for metal ions and resin have better sorption and selectivity properties.
作者 崔元臣 陈权
出处 《环境化学》 CAS CSCD 北大核心 2003年第6期573-577,共5页 Environmental Chemistry
关键词 哌嗪氨基二硫代甲酸 螯合树脂 合成 吸附 哌嗪 二硫化碳 电镀废水 废水处理 piperazine,chelate resin,synthesis,sorption
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