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Synthesis and Crystal Structure of a Novel Polymer Copper(Ⅱ) Complex

Synthesis and Crystal Structure of a Novel Polymer Copper(Ⅱ) Complex
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摘要 A novel chain complex was synthesized and its crystal structure has been deter- mined by X-ray diffraction technique. It was found that the local coordination geometry around Cu(Ⅱ) is a distorted tetrahedron and C14H9CuNO3CH3OH is bridged by the carboxylate oxygen atom to form an infinite one-dimensional linear chain. The hydrogen bond exists between O(1) and solvate molecule O(4). The crystal belongs to monoclinic, space group P21 with a = 9.6650(19), b = 7.1280(14), c = 9.925(2) ? b = 98.39(3)? V = 676.4(2) 3, Z = 2, F(000) = 342 and m(MoK? = 1.629 mm-1 .
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2003年第6期665-668,共4页 结构化学(英文)
关键词 SALICYLALDEHYDE o-aminobenzoic acid crystal structure one-dimensional chain N-salicylidene-2-amino-phenylacidato copper(Ⅱ) 合成 晶体结构 铜(Ⅱ)配合物 共聚体 X-射线衍射分析 一维线性链 单斜晶 N-亚水杨基-2-氨基-苯基酸化铜配合物 C14H9CuNO3·CH3OH
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参考文献15

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