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Synthesis and Structure of Tetraploid (Imidazole) Copper(II) Terephthalate,[Cu(Im)_4](teph) 被引量:2

Synthesis and Structure of Tetraploid (Imidazole) Copper(II) Terephthalate,[Cu(Im)_4 ](teph)
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摘要 The crystal structure of \[Cu(Im)_ 4 \](teph) (Im=imidazole,teph=terephthalate) has been determined by X-ray crystallography. It crystallizes in the triclinic system,space group P ī with cell dimensions of a =0.80356(16) nm, b = 0.84269(17) nm,c =0.88967(18) nm,α =76.90(3)°,β =68.95(3)°,γ =75.94(3)°,and Z =1. Its structure of the title compound is composed of discrete monomeric molecule of \[Cu(Im)_ 4 \]-(teph). The copper(II) ions have a square plane geometry with the CuN_ 4 chromophore. The crystal structure of \[Cu(Im)_ 4 \](teph) (Im=imidazole,teph=terephthalate) has been determined by X-ray crystallography. It crystallizes in the triclinic system,space group P ī with cell dimensions of a =0.80356(16) nm, b = 0.84269(17) nm,c =0.88967(18) nm,α =76.90(3)°,β =68.95(3)°,γ =75.94(3)°,and Z =1. Its structure of the title compound is composed of discrete monomeric molecule of \[Cu(Im)_ 4 \]-(teph). The copper(II) ions have a square plane geometry with the CuN_ 4 chromophore.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2003年第11期1458-1460,共3页 中国化学(英文版)
基金 ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 0 2 75 0 2 0 )andtheNaturalScienceFoundationofShandongProvince (No .Z2 0 0 2B0 2 )
关键词 copper(II) complexes TEREPHTHALATE IMIDAZOLE X-RAY copper(II) complexes,terephthalate,imidazole,X-ray
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  • 1Fangfang Jian,Zuoxiang Wang,Zhiping Bai,Xiaozeng You,Wei Chen.Synthesis, structural and spectroscopic characterization of the α and β forms of bis(imidazole)copper(II) dibenzoate, [Cu(im)2(OBz)2][J].Transition Metal Chemistry.1999(5)
  • 2Melnik,M. Coordination Chemistry Reviews . 1981
  • 3Sigel,H. Inorganic Chemistry . 1980

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