摘要
The crystal structure of \[Cu(Im)_ 4 \](teph) (Im=imidazole,teph=terephthalate) has been determined by X-ray crystallography. It crystallizes in the triclinic system,space group P ī with cell dimensions of a =0.80356(16) nm, b = 0.84269(17) nm,c =0.88967(18) nm,α =76.90(3)°,β =68.95(3)°,γ =75.94(3)°,and Z =1. Its structure of the title compound is composed of discrete monomeric molecule of \[Cu(Im)_ 4 \]-(teph). The copper(II) ions have a square plane geometry with the CuN_ 4 chromophore.
The crystal structure of \[Cu(Im)_ 4 \](teph) (Im=imidazole,teph=terephthalate) has been determined by X-ray crystallography. It crystallizes in the triclinic system,space group P ī with cell dimensions of a =0.80356(16) nm, b = 0.84269(17) nm,c =0.88967(18) nm,α =76.90(3)°,β =68.95(3)°,γ =75.94(3)°,and Z =1. Its structure of the title compound is composed of discrete monomeric molecule of \[Cu(Im)_ 4 \]-(teph). The copper(II) ions have a square plane geometry with the CuN_ 4 chromophore.
基金
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 0 2 75 0 2 0 )andtheNaturalScienceFoundationofShandongProvince (No .Z2 0 0 2B0 2 )