摘要
Based on the different reactivity of selanyl and bromo groups,( E)-α- bromovinylselenides can undergo sequential cross coupling reactions with nucleophiles in the presence of transition metal complexes to form two carbon-carbon bonds in the same olefinic carbon leading to trisubstituted alkenes stereoselectively in good yields.
Based on the different reactivity of selanyl and bromo groups,( E)-α- bromovinylselenides can undergo sequential cross coupling reactions with nucleophiles in the presence of transition metal complexes to form two carbon-carbon bonds in the same olefinic carbon leading to trisubstituted alkenes stereoselectively in good yields.
基金
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 0 0 62 0 0 2 )
