配合物[Cu（C7N5SH7）（H2O）2]Cl2的合成、晶体结构及性质

Synthesis,Crystal Structure and TG Properties of Complex [Cu（C7N5SH7）（H2O）2]Cl2

在N,N-二甲基甲酰胺DMF溶剂中,以3-(3-吡啶基)-氨基-1,2,4-三唑-5-硫酮与CuCl2合成了一个新的配合物[Cu(C7N5SH7)(H2O)2]Cl2,并采用X-射线单晶衍射结构分析方法测定了配合物的晶体结构。配合物是单核分子,Cu2+与两个Cl原子以及三唑硫酮中的S原子和氨基N原子配位,形成四配位化合物。结合标题化合物对其进行了热重性质分析。

We synthesis a new complex[Cu(C 7N 5SH 7)(H 2O) 2]Cl 2 by the 3-amino-5-(pyridin-4-yl)-2H-1,2,4-triazole-3(4H)-thione and CuCl 2 in DMF.X-ray diffraction method was used to analyze the crystal structure of the title compound.The complex is a mononuclear molecule,in which Cu is four-coordinated with two Cl atoms,the S atom and the N atom of the amino from the triazole.The TG property is also reported.