以联苯二胺和水为中心配体的三角三核钼原子簇合物的研究

BENZIDINE AND WATER COORDINATED TRIANGULAR TRINUCLEAR MOLYBDENUM CLUSTER

以簇合物[Mo3O2(CH3COO)6(H2O)3]Br2·2H2O和联苯二胺为原料,在乙醇溶剂中通过置换反应合成出新的三角三核钼簇合物,经紫外光谱分析、红外光谱分析、核磁共振谱分析、元素分析确定该簇合物的组成为[Mo3O2(CH3COO)6(H2O)(NHC6H4C6H4NH2·2H+)2]Br4·10H2O,并确定了该簇合物的结构.

HBr_4·10H_2O was synthesized from Br_2·2H_2O and benzidine by substitution reaction in ethanol and characteized by elemental analysis, UV, IR, and ~1H NMR.