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甲烷气体的冲击化学反应流研究 被引量:1

Studies of chemical reaction flows for gaseous methane under shock compression
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摘要 用二级轻气炮加载技术将W89Mo9Ni1Fe1飞片加速到约5.0km/s,撞击封装有接近常态的甲烷气体的LY12铝靶。利用六通道高温计和示波器记录到冲击压缩的甲烷气体的光辐射历史曲线,并获得甲烷气体的冲击波速度与温度。利用一维Euler方程与化学反应方程的全流场耦合,采用甲烷体系的13组元40反应步的化学反应模型,并用3阶WENO数值格式对空间进行离散。为避免刚性过强,化学反应源项用点隐方法处理。由此得到了甲烷的冲击反应流场和波后热力学参数。通过比较,数值结果与实验结果符合较好。最后,解释了甲烷用作电探针保护气体的物理机制。 Aluminum targets filled with gaseous methane near ambient conditions were impacted by tungsten alloy projectiles which were launched approximately to 5.0km/s from a two-stage light gas gun. The radiant intensities of shock-heated methane varying with time were recorded by means of a six-channel pyrometer and oscilloscopes. The velocities of shock wave and shock temperatures for methane are determined. Eulerian equations coupling with chemical reaction equations involving 13 species and 40-step reactions are solved by using third-order WENO numerical scheme for spatial discretization. The point implicit method is used for chemical source terms to avoid rigid. Then, the chemical reaction flow fields and the thermodynamic properties in the downstream of shock wave are obtained. By comparison, the computational results are agreement with the experimental results. Finally, the physical mechanism of methane applied to as effective atmospheric medium for probes is explained.
出处 《爆炸与冲击》 EI CAS CSCD 北大核心 2003年第6期539-544,共6页 Explosion and Shock Waves
基金 中国工程物理研究院国防科学与技术研究基金项目(2001 421020102 5)
关键词 甲烷 流体力学 反应流场 冲击压缩 电探针 冲击温度 数值计算 二级轻气炮加载技术 fluid mechanics reacting flows shock compression methane probes shock temperature numerical computation
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参考文献1

  • 1MorrisonRT BoydRN 复旦大学化学系有机化学教研组 译.有机化学*上册[M].北京:科学出版社,1980.33-34.

同被引文献7

  • 1Kiefer J H, Kumaran S S. Rate of CH4 dissociation over 2800 - 4300 K: The lower-pressure-limit rate constant[J ]. J Phys Chem, 1994, 97(2): 414-420.
  • 2Kozlov G I, Knorre V G. Single-pulse shock tube studies on the kinetics of the thermal decomposition of methane[J]. Combst Flame, 1962, 6(4): 253-263.
  • 3Marrone P V, Treater C E. Chemical relaxation with preferential dissociation from exited vibrational levels[J]. Phys Fluids,1963, 6(9) : 1215 - 1221.
  • 4Koffi-Kpante K, Zeitoun D, Labracherie L. Computation and experimental validation of N-CH-Ar mixture flows behind normal shock wave[J]. Shock Waves, 1997, (7) : 351 - 361.
  • 5唐敬友,谷岩,胡海波,彭其先,王贵朝,董庆东.冲击压缩下甲烷的状态参数实验研究[J].流体力学实验与测量,2001,15(4):30-35. 被引量:6
  • 6唐敬友,岳鹏涛,徐胜利,谷岩,董庆东.电探针保护气体的优选原则[J].流体力学实验与测量,2003,17(1):28-31. 被引量:2
  • 7唐敬友,岳朋涛,谷岩,胡海波,徐胜利,董庆东.甲烷气体的冲击状态方程数值计算[J].空气动力学学报,2003,21(2):164-172. 被引量:3

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