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聚磷酸蜜胺系膨胀型阻燃剂阻燃PA6的燃烧行为及热裂解研究 被引量:8

Combustion Behavior and Thermal Pyrolysis of PA6 Flame-Retarded with Melamine Polyphosphate Based Intumescent Flame Retardants
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摘要 采用以聚磷酸蜜胺 (MPP)为基的三元膨胀型阻燃剂阻燃聚酰胺 6(PA6) ,测定了阻燃PA6的氧指数 (LOI)、UL94V阻燃性及热稳定性 ,以傅立叶变换红外光谱 (FT IR)分析了阻燃PA6的热分解残余物 ,以锥形量热仪(CONE)测定了阻燃PA6的诸多与火灾有关的阻燃参数 (包括释热速度、质量损失速度、有效燃烧热、比消光面积等 ) ,并以光电子能谱 (XPS)测定了阻燃PA6残炭表面的元素组成及XPS曲线拟合数据。 PA6 was flame retarded with melamine polyphosphate based tertiary intumescent flame retardants(IFR).The limiting oxygen index,UL94V flame retardancy and thermal stability of the flame retarded PA6 were measured.The FT IR technique was used to analyze the pyrolysis residue and the cone calorimeter was applied to determine a number of combustion parameters which are closely related to fire safety,including heat release rate,mass loss rate,effective combustion heat,specific extinction area,etc..In addition,the elemental composition of the pyrolysis residue on PA6 surface and the corresponding XPS data were obtained using XPS technique.
出处 《中国塑料》 EI CAS CSCD 北大核心 2003年第11期61-64,共4页 China Plastics
关键词 聚酰胺6 膨胀型阻燃剂 聚磷酸蜜胺 polyamide 6 intumescent flame retardant melamine polyphosphate
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参考文献6

  • 1彭治汉 郑现国 姚亮红.无卤阻燃尼龙6工程塑料[A]..新世纪聚酰胺发展战略研讨会论文集[C].北海:中国石油化工集团聚酰胺技术开发中心,2002.88~93.
  • 2吴俊浩.[D].北京理工大学材料科学与工程学院,2002.
  • 3欧育湘.国外阻燃剂发展动态及对发展我国阻燃剂工业之浅见[J].精细与专用化学品,2003,11(2):3-6. 被引量:76
  • 4K A Hughes, J Bohan, J Say, et al. Advances in Flame Retardant Polyamide [ C ]. The Proceedings of American FRCA Conference. Lancaster (PA) : American FRCA, March, 2000.85 -89.
  • 5A Mukherijee. Melamine Derivatives-an Alternative to Traditional Flame Retardants [J]. Plastics Engineering, 2001,(2) :42 -46.
  • 6A Mukherijee. Melamine Derivatives as Flame Retardant Additives in Polymers[ C ]. The Proceedings of American FRCA Conference. Lancaster(PA) : American FRCA, March, 2000.119-127.

二级参考文献9

  • 1[3]Fisch H, in "The Proceedings of the International Conference on Flame Retardant Technologies". Tokyo, Nov. 2001,13~14
  • 2[4]Sanders D. 同[3],124
  • 3[5]Enitorial. FRCA Newsletter,2002,26(1):7
  • 4[7]Editorial. Plastics Technology,2001,47(1):27
  • 5[8]ibid. 2000,46(2):31
  • 6[9]ibid. 2000,46(4):40
  • 7[11]Editorial. Polymer News,2001,26(2) :59
  • 8[12]同[7]. 2000,46(3):33
  • 9[13]Editorial. Modern Plastics, 1998,(9):42~44

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同被引文献90

引证文献8

二级引证文献40

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