神华煤直接液化转化率及收率与温度和时间的关系

Influence of reactive temperature and time on conversion and yield of Shenhua coal direct liquefaction

通过实验考察了反应温度和反应时间对神华煤直接液化性能的影响,研究了煤转化率及各产物收率与反应温度和反应时间的关系。实验结果表明,反应温度和反应时间对煤直接液化性能的影响存在交互作用,在一定范围内,在较低的反应温度、较长的反应时间下的煤转化率可以达到和较高反应温度、较短反应时间时差不多,但是液化油收率相对低一些。使用Origin软件对实验数据进行曲面拟合,得到了煤转化率及各产物收率与反应温度和反应时间的关系表达式。每个关系式的校正判定系数都大于0. 95,说明拟合结果较为理想。

The effects of reaction temperature and reaction time on the direct liquefaction performance of Shenhua coal are investigated via experiments.Relationship of coal conversion and product yield to both reaction temperature and reaction time is studied.The experimental results illustrate that the reaction temperature and reaction time has interaction effects on direct coal liquefaction performance.In a certain range,the coal conversion that can be achieved at a lower reaction temperature and a longer reaction time is close to that at a higher reaction temperature and a shorter reaction time,but the liquefaction oil yield is a bit lower.The expressions of relationship of coal conversion and each product yield to both reaction temperature and reaction time are obtained by using Origin software with surface fitting module to fit the experimental data.The adjustment R-Square of each relation is greater than 0.95,indicating that the fitting results of correlations with these relations are relative satisfactory.