含Ph2PPy配体的络合物的合成及催化性能

Synthesis and catalytic properties of some mononuclear and dinuclear complexes containing diphenylpyridylphosphine（Ph2PPy）

合成了二苯基吡啶基膦配体（Ph2PPy）,以及该配体与Fe、Co、Ni等单核和Fe-Rh、Co-Rh、Ni-Rh等双核络合物。评价了这些络合物催化剂对甲醇羰基化反应的催化性能。

A ligand diphenylpyridylphosphine(Ph_2PPy), some mononuclear complexes from the ligand and Fe,Co,Ni and dinuclear complexes from the ligand and Fe-Rh,Co-Rh,Ni-Rh have been synthesized. The catalytic properties of these complexes for the reaction of carbonylation of methanol are evaluated.