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制备条件对改性MCM-41催化性能的影响 被引量:4

Influence of the Preparative Condition on Catalytic Activity in Modified MCM-41 Molecular Sieves
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摘要 用浸渍法将SO42 -/ZrO2 引入到MCM - 4 1中 ,用XRD、IR、Py -IR等技术对其进行表征 ,并考察了制备条件对苯与丙烯气相流动反应的催化活性影响。结果表明 ,适宜的制备条件可制得对苯与丙烯烷基化反应有良好催化活性的SO42 -/ZrO2 -MCM - 4 Super acidic Catalyst SO 4 2- /ZrO 2 were introduced int o pure silicone MCM-41 by macerating method and characterized by XRD, IR, and Py-I R. Effect of the preparative condition on catalytic synthesis of iso-propyl benz ene in the catalysts has been tested. The result shows that the catalyst shows h igher conversion for the propene and higher selectivity for the iso-propyl benze ne when the SO 4 2- /ZrO 2-MCM-41 was prepared in some condition.
出处 《长春理工大学学报(自然科学版)》 2003年第4期7-9,12,共4页 Journal of Changchun University of Science and Technology(Natural Science Edition)
基金 教育部留学人员科研启动基金 长春理工大学科研启动基金资助
关键词 丙烯 异丙苯 改性MCM-41 超强酸催化剂 催化性能 制备条件 Benzene Propene Iso-propyl benzene Modified MCM-41 Super acidic catalyst
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参考文献12

  • 1Casci J L, Stud. Surf. Sci. Catal. , 1994, 85:329
  • 2Sayari A, Chem. Mater. , 1996, 8:1840
  • 3Corma A, Chem. Rev. , 1997, 97:2373
  • 4Yang H, Kuperman A, Coombs N, et al., Nature,1996, 379:703
  • 5Feng X, Fryxell F, Wang L Q, et al. , Science, 1997,276:923
  • 6雷霆,华伟明,唐颐,乐英红,高滋.MCM-41负载SO_4^(2-)/ZrO_2超强酸的性能研究[J].高等学校化学学报,2000,21(8):1240-1243. 被引量:42
  • 7Chem C L, Cheng S, Lin H P, Wong S T, Mou C Y,Appl. Catal. A, 2001, 215:21
  • 8Kozhevikov I V, Sinnema A, et al, Catal. , Lett. ,1995, 30:241
  • 9Blasco T, Corma A, Martinez A, J Catal. , 1998, 178:207
  • 10Yamaguchi T, Tanabe K, Maters. Chem. And Phys. , 1986, 16:67

二级参考文献6

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同被引文献28

  • 1Davis, C. Saldarriage, C. Montes, J. Garces, C.Cravder, Nature, 1998, 331
  • 2I. V. Kozhevikov, A. Sinnema, et al., Catal Lett,1995, 30, 241
  • 3T. Blasco, A. Cormal, A. Martinez, J. Catal. 1998,177, 306
  • 4R. H. Janes, J. M. Thomas, J. Chen, R. Xu, etal.,J. Sol. Stat. Chem., 1993, 102, 204
  • 5Khushalani D, Kuperman A, Coombs N, etal, Chem. Mater., 1996, 8, 2188
  • 6C. Y. chen, S. L. Burkett, H. X. Li, etal, Microporous Mater., 1993, 2, 227
  • 7P. T. Tanev, M. Chibwe, T. J. Pinnavaia, Nature,1994, 368, 321
  • 8S. A. Bagshaw, T. J. Pinnavaia, Science, 1995, 268,1242
  • 9T. Corma, M. T. Navarro, J. Perez- Pariente, Chem.Commun. , 1994, 147
  • 10K. A. Koyano, T. Tatsumi, Chem. Commun., 1996,145

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