Kaminsky催化剂的发展对配位聚合实践和理论的影响

The Development of Kaminsky Catalyst Has an Effect on the Theory and Practise of Coordination Polymerization

本文介绍了Kaminsky可溶性配位催化剂的发展特点,并在总结均相催化定向控制机理、α-烯烃的间规聚合以及聚合活性种的性质等方面的最新研究成果基础上,讨论了对配位聚合理论研究的意义。

This review covered the development and the major eharacteristies about the soluable coordination catalysts discovered by Kaminsky. Its meaning to the theory research of coordination polymerization had been described through recent research progress in the stereo-control mechanism of homogenous catalysis, the syndiotatic polymerization of α-olefins as well as the properties of polymeric active centers.