摘要
The extraction of thallium (Ⅲ) with di (2-ethylhexyl) sulfoxide from hydrochloric acid media was studied by means of single-drop method.An extraction rate expression and the activation energysupport a mechanism,in which the ratelimiting step is HTlCl4+DEHSO(i) =HTlCl4DEHSO(i).
The extraction of thallium (Ⅲ) with di (2-ethylhexyl) sulfoxide from hydrochloric acid media was studied by means of single-drop method. An extraction rate expression and the activation energysupport a mechanism, in which the ratelimiting step is HTlCl_4+DEHSO(i)=HTlCl_4DEHSO(i).
出处
《苏州大学学报(自然科学版)》
CAS
1991年第2期221-226,共6页
Journal of Soochow University(Natural Science Edition)
关键词
动力学
铊(Ⅲ)
硫氧化物
盐酸
Thallium (Ⅲ)
Extraction kinetics
Di(2-ethylkexyl)sulfoxide