摘要
In this study,the possibility of obtaining micro and nano-scaled Co/Ni bi-layered films by use of the electrochemical method was investigated.The electrodeposition process was performed with presence and absence of a uniform external magnetic field up to 1T to examine its influence on structure and morphology of the obtained thin films. Afterwards,each sample was annealed under high magnetic field with strength up to 12 T at 623 K,what allowed compare and determine the changes in morphology and structure,before and after heat treatment.The Co/Ni bi-layered thin films were deposited onto an indium-doped tin oxide(ITO)-coated conducting glass substrate from sulfate baths with boric acid as an additive.The results show drastic changes in the morphology between macro and nano-scaled films which were strongly affected by an introduction of the magnetic field to the electrodeposition process.The annealing process allowed to determine the nucleus transition and showed that under the high temperature treatment it is possible to control the growth mode as well as the phase composition changes.
In this study,the possibility of obtaining micro and nano-scaled Co/Ni bi-layered films by use of the electrochemical method was investigated.The electrodeposition process was performed with presence and absence of a uniform external magnetic field up to 1T to examine its influence on structure and morphology of the obtained thin films. Afterwards,each sample was annealed under high magnetic field with strength up to 12 T at 623 K,what allowed compare and determine the changes in morphology and structure,before and after heat treatment.The Co/Ni bi-layered thin films were deposited onto an indium-doped tin oxide(ITO)-coated conducting glass substrate from sulfate baths with boric acid as an additive.The results show drastic changes in the morphology between macro and nano-scaled films which were strongly affected by an introduction of the magnetic field to the electrodeposition process.The annealing process allowed to determine the nucleus transition and showed that under the high temperature treatment it is possible to control the growth mode as well as the phase composition changes.
基金
Item Sponsored by National Natural Science Foundation of China(51061130557,51101032)
French ANR,Champagne-Ardenne Region Council and Pole MATERALIA(Programme COMAGNET,Grant No.2010-INTB-903-01)
