双(2,2-二硝基丙基)肼甲硼氢络合物的合成及性能研究

Synthesis and Properties of Bis-(2,2-dinitropropyl)-hydrazine Borane Complex

本文报道了双(2,2-二硝基丙基)肼甲硼氢络合物的合成及其性能。实验表明,该络合物在较低温度下(0～5℃)有一定安定性,放置几天后,基本不变,在稍高温度下(20～25℃)放置1～2小时即迅速分解,自燃或自爆。此外,还讨论了可能的机理。

Reaction of 2,2-dinitropropyl hydrazine wtih diborane in ether at frozentemperature yields bis-(2,2-dinitropropyl)hydrazine borane complex in white crystallineform.At lower temperature(0-5℃) it can last for several days,but at higher temperature(20-25℃) it decomposes rapidly and ignites or explodes within 1-2 hours.