连续二氧化碳激光敏化氧化CF_2 HCl,CF_2=CF_2,CF_2=CFCl,CHCl_3,CHCl=CCl_2和CH_2=CH_2

CW-CO_2 Laser Sensitized Oxidation of CF_2 HCl,CF_2=CF_2,CF_2=CFCI,CHCI_3,CHCI=CCI_2 and CH_2=CH_2

本文报道了连续二氧化碳激光敏化氧化CF_2HCl,CF_2==CF_2,CF_2==CFCL,CHCl_3,CHCl==CCl_2和CH_2==CH_2的反应,讨论了某些反应的机制。结果表明,激光敏化方法可以使不能直接吸收激光的反应物分子在气相中发生反应,并有可能产生卡宾。

This paper reports the CW-CO_2 laser sensitized oxidation reactions of thetitle compounds and discusses the mechanisms of some reactions.The experiments showthat the reactions of the reactive molecules,which can not absorb laser beam directly,could be carried out by laser sensitized method in the gas phase and it is possible to pro-duce the carbenes.