摘要
在常压下采用U形振动管密度计测定了对二甲苯与环丁砜的混合液在298 15K~353 15K下的密度,用乌氏粘度计测定了此混合溶液在303 15K~353 10K下的粘度,并由密度数据计算出超额体积VE、由粘度数据计算出了不同温度和组成下的混合粘度的变化,同时对不同温度下的超额体积与组成的关系进行了多元回归,对混合粘度变化随组成的关系按Redlich-Kister方程进行了关联。
Densities and viscosities of the binary mixture of sulfolane with p-xylene were determined between 30315 to 35315K at atmospheric pressure by using a vibrating U-shaped sample tube densimeter and Ubbelohde suspended-level viscometer respectively.Density values were used in determination of excess molar volume.Viscosities were used to calculated deviations of viscosity.Excess volume and deviation of viscosity were fitted by a multiple regression analysis and Redlich-Kister equation respectively.
出处
《化学工业与工程》
CAS
2004年第1期12-16,共5页
Chemical Industry and Engineering