摘要
烃类氧化反应是石油化工中一类重要反应。空气和氧气是容易得到且环境友好的氧化剂,所以以氧为氧化剂的具有高选择性和转化率的催化体系的开发在烃类氧化中具有极其重要意义。本文在对传统的烃类分子氧氧化催化剂进行讨论的基础上,对近年来出现的以N-羟基邻苯二甲酰亚胺为基础的新催化剂体系进行了综述。该催化体系催化的烃类分子氧氧化反应具有反应条件温和、选择性高等优点。
The oxidation of hydrocarbons is a main kind of reaction in chemical industry.Since oxygen or air is abundant and environmentally clean,it is very attractive to develop oxidation process with molecular oxygen as oxidant.Recently a novel catalytic system based on N-hydroxyphthalimide for the oxidation of varieties of hydrocarbons has been reported.Using this catalytic system,the oxidation reactions proceed under mild conditions and give both high conversions and selectivities.In the paper,this novel catalytic system and all the reactions catalyzed were reviewed.
出处
《化学工业与工程》
CAS
2004年第1期38-42,共5页
Chemical Industry and Engineering
关键词
烃
分子氧氧化
催化氧化
N-羟基邻苯二甲酰亚胺
hydrocarbons
molecular oxygen oxidation
catalytic oxidation
N-hydroxyphthlimide
