摘要
培养了苦味酸锂与二苯并18-冠-6缔合物的单晶体[Li（pic）（H<sub>2</sub>O）]<sub>2</sub>·[C<sub>20</sub>H<sub>24</sub>O<sub>6</sub>],化学式为C<sub>32</sub>H<sub>32</sub>Li<sub>2</sub>N<sub>6</sub>O<sub>22</sub>,用X射线法测定了缔合物的晶体结构,证明该晶体属单斜晶系,空间群为P2<sub>1</sub>/m,晶胞参数:a=8.299（2）,b=25.216（3）,c=9.158（2）（?）,β=100.34（2）°,V=1885.4（?）<sup>3</sup>,Z=2。
The title single crystal of the associated molecule [Li(pic)(H2O)]2 ?[(C20H24O6)] has been perpared and characterized by elemental analysis, X-ray single crystal diffraction. The crystal belongs to the monoclinic system and the space group is P21 / m with crystal parameters a=8.299(2), b = 25.216(3), c=9.158(2)A, β= 100.34(2)°, V= 1885.4A3, Z = 2, D0=1.53, Dc= l.526g/ cm3, n= 1.216cm-1.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1992年第3期323-325,共3页
Chinese Journal of Inorganic Chemistry
