大环配体过渡金属配合物——Ⅵ.四(对-二硫杂环己烯)四氮杂卟啉钒(Ⅳ)、锰(Ⅱ)和钼(Ⅴ)配合物的合成与表征

TRANSTION METAL COORDINATION COMPOUNDS OF MACROCYCLIC LIGAND VI. SYNTHESES AND CHARACTERIZATION OF TETRA (1,4-DITHIACYCLOHEXENE)TETRAAZAPORPHYRIN COORDINATION COMPOUNDS WITH V(IV), Mn(II), AND Mo(V) IONS

d过渡金属含硫四氮杂卟啉配合物,是一类新型功能性配合物,因其具有比金属卟啉、金属酞菁更为优异的光电和催化特性,故近十多年来颇受重视。我们对该类金属配合物及其自由配体的合成、性质和某些功能,正在进行广泛和深入的研究。本文简要报道标题配合物的合成、元素分析,红外光谱、电子光谱和电子顺磁共振谱的表征。

In the basic of rcfcrrencc [6]> and [7] , the title compounds VCl2TTTAP, MnTTTAP, and MoO(OH)TTTAP have been synthesized according to the solid reaction method from prepared 2,3-dicyano-1,4-dithiacyclohcxcnc and metal acetate. Study has been made of the infrared and electronic spectra for the transition metal coordination compounds of this ligand in combination with rcfcrrencc [6] . The TTTAP system is similar to PC and TAP (tctraazapor-phyrin) et al. systems in infrared and electronic spectra.