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聚丙烯/聚苯乙烯共混体系模量的细观力学研究 被引量:3

STUDY ON THE ELASTIC MODULUS POLYPROPYLENE/POLYSTYRENE BLENDS BY MESO-MECHANICS
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摘要  应用复合材料细观力学理论和相应分析模型,预测了聚丙烯/聚苯乙烯(PP/PS)共混体系的弹性模量并进行相应的试验研究。系统研究了非相容PP/PS共混物的体积含量和共混时间对共混物形态和弹性模量的影响,分析了细观形态与宏观力学性能间的关系。对PP/PS共混物的拉伸实验结果表明:微观力学模型在模量预报上是可行的,其中Mori-Tanaka法更有效,因为与半经验模型(如Halpin-Tsai法和改进的混合模型)相比,它没有试验参数,在材料设计时具有更大的优越性。 The elastic modulus of polypropylene/polystyrene (PP/PS) blend was predicted by means of meso-mechanics of composite materials. Based upon the systematical studies of the effects of composition and mixing time on the elastic modulus and morphology of immiscible blends PP/PS, the relation of microscopic morphology and macroscopic mechanical property was discussed. Tensile tests showed that the meso-mechanical models were valid for the prediction of elastic modulus and the Mori-Tanaka model would be a more effective method for designing materials in comparison with other models such as Halpin-Tsai model and modified mixture model because there is no restriction on the experimental parameters.
出处 《复合材料学报》 EI CAS CSCD 北大核心 2003年第2期100-105,共6页 Acta Materiae Compositae Sinica
基金 国家自然科学基金重点项目(59733070)
关键词 形态 力学特性 非相容的共混物 细观力学 Composite materials Elastic moduli Mechanical properties Morphology Tensile testing
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