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某些烟煤镜质组氯仿抽出物及其萤光性的初探 被引量:1

CHLOROFORM-EXTRACT OF SOME BITUMINOUS VITRINOID GROUP AND THEIR FLUORESCENCE STUDY
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摘要 作者研究了煤化度相近的两组煤镜质组氯仿抽出物及其石油醚抽出物的萤光参数。研究表明,它们均发荧光,且荧光光谱没有大的区别,仅红绿商 Q 和最大荧光强度波长λ_(max)差别较大。~1H-NMR 分析表明,两组煤的氢分布差异较大,第一组煤镜质组氯仿抽出物的脂肪氢含量较丰富。 The fluorescence parameters of the chloroform extract and petroleum ether extract of two groups of vitrinoid of somewhat similar coalification are studied.Both groups give fluores- cence;and their fluorimetric spectra are not greatly different from each other except for some dis- tinct difference in Q(red/green)and λ_(max)(wavelength of maximum fluorescent intensity).~1H- NMR analysis shows:there is a considerable difference in hydrogen distribution of the two groups,with the CHCl_3 extract from the lst vitrinoid group more abundant in paraffinic hydro-
出处 《武汉钢铁学院学报》 1992年第4期353-359,共7页
关键词 镜质组 氯仿抽出物 荧光性 coal vitrinoid group chloroform extract fluorescence
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  • 1周师庸,叶菁,袁庆春,奚白,刘云,周淑仪.炼焦煤荧光光谱和红绿商[J].燃料与化工,1995,26(3):107-113. 被引量:5
  • 2赵长毅.显微组分荧光机理及其应用[J].石油勘探与开发,1996,23(2):8-10. 被引量:11
  • 3王飞宇,郝石生,何萍,刘德汉.不同类型镜质体荧光特征差异性及原因[J].沉积学报,1997,15(2):164-168. 被引量:3
  • 4Wang Z C, Hu J C, Shui H F et al. Study on the structure and as- sociation of asphaltene derived from liquefaction of lignite by fluo- rescence spectroscopy[J]. Fuel, 2013, 7 (109): 94 - 100.
  • 5Sun X G. The investigation of chemical structure of coal macerals via transmitted - light FT - IR microspectroscopy[ J]. Spectrochim- ica Acta Part A, 2005, 62 : 557 - 564.
  • 6Li W, Zhu Y M, Chen S Bet al. Research on the structural charac- teristics of vitrinite in different coal ranks[ J]. Fuel. 2013, 107: 647 - 652.
  • 7Fan J J, Liu K Y, Ju Y Wet al. Total scanning fluorescence char- acteristics of coals and implication to coal rank evaluation[ J]. Jour- nal of Geological Research. 2012, 4(22) : 1 -6.
  • 8Lin R. Vitrinite secondary fluorescence:Its chemistry and relation to the development of a mobile phase and thermoplasticity in coal [ J]. International Journal of Coal Geology, 1986, V. 6 : 215 - 228 .
  • 9吴俊.同煤化程度不同煤层煤荧光性的研究及其应用[J].贵州地质,1988,6(2):175-184.
  • 10虞继舜,肖风娟.煤的粘结性、荧光性与还原性的研究[J].煤炭分析及利用,1992,(2):13-19.

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