期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

手性亚磷酸酯-铑络合物催化的烯烃氢甲酰化反应 被引量：1

原文传递
导出
摘要 设计和合成了一系列由联二萘酚衍生的手性亚磷酸酯配体.这些配体与铑(Ⅰ)形成的络合物能够有效地催化苯乙烯和乙酸乙烯酯的不对称氢甲酰化反应,显示高度的催化活性、化学选择性和较好的区域选择性(异构醛/正构醛).最高对映选择性分别达到37.0％和38.1％.手性双齿亚磷酸酯配体与单齿亚磷酸酯配体相比,产生更好的对映选择性,但是更低的区域选择性.
作者 鄢明 黎星术 陈新滋
机构地区 苏州大学化学化工学院 香港理工大学应用生物与化学科技系
出处 《科学通报》 EI CAS CSCD 北大核心 2003年第15期1633-1637,共5页 Chinese Science Bulletin
基金 苏州大学科研启动基金 香港理工大学ASD基金资助项目.
关键词 手性亚磷酸酯-铑络合物 催化 烯烃 氢甲酰化反应
分类号 O621.25 [理学—有机化学]
  • 相关文献

参考文献15

  • 1[1]Gladiali S, Bayon J, Claver C. Recent advances in enantioselective hydroformylation. Tetrahedron: Asymmetry, 1995, 6(7): 1453～ 1474
  • 2[2]Agbossou F, Carpentier J F, Mortreux A. Asymmetric hydroformylation. Chemical Reviews 1995, 95(7): 2485～2506
  • 3[3]Nozaki K, Sakai N, Nanno T, et al. Highly enantioselective hydroformylation of olefins catalyzed by rhodium(Ⅰ) complexes of new chiral phosphine-phosphite ligands. Journal of American Chemical Society, 1997, 119(19): 4413～4423
  • 4[4]Dieguez M, Pamies O, Ruiz A, et al. Asymmetric hydroformylation of styrene catalyzed by carbohydrate diphosphite-Rh(Ⅰ) complexes. New Journal of Chemistry, 2002, 26(7): 827～833
  • 5[5]Aghmiz A, Masdeu-Bulto A M, Claver C, et al. Rhodium-cata- lysed asymmetric hydroformylation of vinylarenes with chiral P,N-ligands based on DIOP skeleton. Journal of Molecular Catalysis A: Chemical, 2002, 184: 111～119
  • 6[6]Freixa Z, Bayon J C. Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring. Journal of Chemical Society, Dalton Trans, 2001, (14): 2067～2068
  • 7[7]Jiang Y Z, Xue S, Li Z, et al. Asymmetric synthesis. Part 29: Asymmetric hydrofromylation of styrene catalyzed by chiral spiro diphosphite-rhodium(Ⅰ) complexes. Tetrahedron: Asymmetry, 1998, 9(18): 3185～3189
  • 8[8]Yan M, Chan A S C. Enantioselective conjugate addition of diethylzinc to cyclic enones with chiral aryl diphosphite-copper catalysts. Tetrahedron Letters, 1999, 40(36): 6645～6648
  • 9[9]Yan M, Zhou Z Y, Chan A S C. Conjugate addition of diethylzinc to α, β-unsaturated lactones catalyzed by copper-phosphite complexes. Chemical Communications, 2000, 115～116
  • 10[10]Yan M, Xu Q Y, Chan A S C. Asymmetric hydrocyanation of olefins catalyzed by chiral diphosphite-nickel complexes. Tetrahedron: Asymmetry, 2000, 11(4): 845～849

同被引文献9

  • 1GLADIALI S,BAYON J C,CLAVER C.Recent advances in enantioselective hydroformylation[J].Tetrahedron:Asymmetry,1995,6:1453-1474.
  • 2DIEGUEZ M,PAMIES O,CLAVER C.Recent advances in Rh-catalyzed asymmetric hydroformylation using phosphite ligands[J].Tetrahedron:Asymmetry,2004,15:2113-2122.
  • 3BABIN J E,WHITEKER G T.Preparation of catalyst ligands for asymmetric hydroformylation[p].WO 93/03839.
  • 4DIEGUE M,PAMIES O,RUIZ A.Asymmetric hydroformylation of styrene catalyzed by carbohydrate diphosphite-Rh(Ⅰ) complexes[J].New J Chem,2002,26:827-833.
  • 5BUISMAN G J H,VOS E J,KAMER P C J.Hydridorhodium diphosphite catalysts in the asymmetric hydroformylation of styrene[J].J Chem Soc,Dalton Trans,1995:409-417.
  • 6NOZAKI K,SAKAI N,NANNO T.Highly enantioselective hydroformylation of olefins catalyzed by rhodium(Ⅰ) complexes of new chiral phosphine-phosphite ligands[J].J Am Chem Soc,1997,119:4413-4423.
  • 7SUAREZ A,MENDEZ-ROJAS M A,PIZZANO A.Electronic differences between coordination functionalities of chiral phosphine-phosphites and effects in catalytic enantioselective hydrogenation[J].Organometallics,2002,21:4611-4621.
  • 8BAKER M J,PRINGLE P G.A tetraphos ligand with C3 symmetry[J].J Chem Soc,Chem Commun,1993:314-316.
  • 9SUAREZ A,PIZZANO A.New chiral phosphine-phosphites:a convenient synthesis based on the demethylation of o-anisyl phosphines and application in highly enantioselective catalytic hydrogenation[J].Tetrahedron:Asymmetry,2001,12:2501-2504.

引证文献1

科学通报
2003年 第15期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部