期刊文献+

α-MnO_2及掺杂Ti的研究 被引量:2

A Study of α-MnO_2 and α-MnO_2 Doped with Titanium
下载PDF
导出
摘要 探讨了3×3隧道结构的α二氧化锰的合成以及掺杂Ti前后的电化学性能,结果表明摻杂后可充性明显改善,X衍射的结果表明经过有限的充放电过程,α二氧化锰的晶体结构基本得以保留。红外光谱的结果显示,掺杂的Ti不是简单的TiO_2的形式。 3×3 structure α-MnO2 was synthesized and doped with titanium. 1 s electrochemical characteristic is discussed in the article. It shows that the rechargeabihty of α-MnO2 is evidently improved by doping with titanium. X-ray diffraction indicates that the structure of α-MnO2 remains much the same after limited discharging and charging time. IR spectrum shows that the structure of titanium as dopant in α-MnO2 is different from that of pure TiO2.
出处 《材料导报》 EI CAS CSCD 2003年第F09期256-259,共4页 Materials Reports
关键词 α-MnO2 α二氧化锰 电化学性能 晶体结构 红外光谱 可充性电池 α-MnO_2, analysis by charged and discharged,X-ray diffraction ,IR spectrum
  • 相关文献

参考文献10

  • 1Kordesch K. U S Pat, 4105830. 1978-08-08
  • 2Kordesch K, Gsellmann J, et al. The rechargeability of manganese dioxide in alkaline electrolyte [J]. Electrochim Acta, 1981,26 : 1495
  • 3Naetey V K, Binder L, et al. Production and characterisation of titanium doped electrolytic manganese dioxide for use in rechargeable alkaline zinc/manganese dioxide batteries [J]. J Power Sources ,2000,87: 205
  • 4童庆松,甘晖,连锦明,张其昕.掺铋电解二氧化锰可充性研究[J].电池,1997,27(1):14-17. 被引量:10
  • 5Castledine C G,Conway B E, et al. Effects of electrochemicalloy incorporated bismuth on the discharge and recharge of electrodeposited manganese dioxide film in 9 M aqueous KOH [J]. J Appl Electrochem, 1995,25: 707
  • 6Bode M, Cachet C, et al. Rechagebility of MnO2 in KOH media produced by decomposition of dissolved KMnO4 and Bi(NO3)3 mixures [J]. J Electrochem Soc, 1997,144(3):792
  • 7夏熙,郭再萍.可充碱锰电池进展[J].电池,1997,27(6):249-254. 被引量:13
  • 8Roberto N De Guzman,Shen Yan-Fei,et al. Role of Cyelic Voltammetry in Characterizing Solids: Natual and Sybthetic Manganese Oxide Octahedral Molecular Sieves [J].Chem Mater, 1993,5:1395
  • 9夏熙.可充碱锰电池发展与展望[J].电池,1994,24(2):78-83. 被引量:9
  • 10Wolfgang Jantscher, Leo Binder, et al. Synthesis, characterization and application of doped electrolytic manganese dioxides [J]. Power Sources, 1999,79 : 9

二级参考文献4

共引文献29

同被引文献18

  • 1潘军青,万平玉,孙艳芝,王子镐,刘小光.纳米铋酸钠的合成及其结构表征[J].高等学校化学学报,2004,25(12):2204-2207. 被引量:5
  • 2章明,焦丽芳,袁华堂,赵明,王永梅.MoO_3氧化物掺杂改善LiFePO_4/乙炔黑电化学性能研究[J].无机化学学报,2006,22(5):839-844. 被引量:10
  • 3KORDESCH K, GSELLMANN J, PERI M, et al. Study on rec2hargeable nranganese dioxide battery [J]. Electrochim Acta, 1981,26:1 495.
  • 4KORDESCH K, GSELLMANN J. Effect of additives on the rec2harge behaviour of manganese dioxide [ P]. USP : 4384039, 1983205217.
  • 5RWOBLOWA H S, GUPTA N. Rechargeable manganese, oxide elec2trodes: part II, physically modified materials [J]. J ElectroanalChem, 1987, 2.38: 93 - 102.
  • 6Wroblowa H S, Gupta N. Electrochemical properties of Layer manga- nese dioxide [J]. J. Electroanal. Chem. , 1981, 238: 93.
  • 7Park S-J, Kim S, Lee S, et al. [J]. J Am Chem Soc, 2000,122(35): 8581-8582.
  • 8Wilcoxon J P, Provencio P P. [J]. J Phys Chem, B, 1999,103(45): 9809-9812.
  • 9Zhang D, Klabunde K J, Sorensen C M, et al. [J]. Phys Rev B, 1998, 58(21): 14167-14170.
  • 10Malow T R, Koch C C. [J]. Metall Mater Trans A, 1998,29(9): 2285-2295.

引证文献2

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部