水杨醛缩氨基硫脲铁(Ⅲ)配合物的固相合成、表征及X-射线指标化

Solid Phase Synthesis,Characterization and X-ray Indexing of Salicylaldehyde Thiosemicarbazone Complexes of Iron(Ⅲ)

水杨醛缩氨基硫脲与三氯化铁通过固相反应,合成了新的配合物[Fe(C8H8N3OS)2]Cl·3H2O。经元素分析、X＿射线粉末衍射、红外光谱和电子光谱,确定了其组成和结构。对XRD谱进行指标化,确定了配合物的晶系和晶胞参数。

The new Salicylaldehyde thiosemicarbazone complexes of Iron (Ⅲ),[Fe(C_8H_8N_3OS)_2]Cl·3H_2O] were synthesized by the Soild Phase Reaction.The complexes have been characterized by the element analysis,X_ray powder diffraction,IR spectrum electronic spectrum.The crystalline structure of the complexes to triclinic system.The lattice parameters are a=0.7064nm,b=1.5695nm,c=1.9115nm,α=88.08°,β=94.38°,γ=98.82°.In the complexes,N,O and S atom coordinate to the Fe ion.