摘要
The new complex [Ce(CH2=C(CH3)COO)2(NO3)(Phen)]2 was prepared in ethanol- a queous solution with 8- hydroxyquinoline as the acidity regulator. Its crystal structure was determined by X- ray diffraction analysis. The title complex is t riclinic, space group P1, a=1.00832(3)nm, b=1.02858(8)nm, c=1.12350(8)nm, α =11 3.9250(10)° , β =103.8210(10)° , γ =81.4650(10)° , V=1.03252(14)nm3, Z=1, D c=1.700g· cm- 3, F(000)=522. The coordination number of Ce3+ is nine. CCDC: 211278.
The new complex [Ce(CH2 = C(CH3) COO) (2) (NO3) (Phen) ](2) was prepared in ethanol-aqueous solution with 8-hydroxyquinoline as the acidity regulator. Its crystal structure was determined by X-ray diffraction analysis. The title complex is triclinic, space group P1, a = 1.00832(3) nm, b = 1.02858(8) nm, c = 1.12350(8) nm, a = 113.9250(10)degrees, beta = 103.8210(10)degrees, gamma = 81.4650(10)degrees, V = 1.03252(14) nm(3), Z = 1, D-c = 1.700g . cm(-3), F(000) = 522. The coordination number of Ce3+, is nine.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2003年第9期1030-1032,共3页
Chinese Journal of Inorganic Chemistry
基金
上海市青年基金资助项目(No.2000QN34)。
