含茂、非茂混合配体钛族络合物的合成与催化烯烃聚合的研究进展

Progress in Synthesis of Group 4 Complex with Cp and Non-Cp Mixed Ligands and Their Catalytic Application for α-Olefin Polymerization

目前金属有机钛族络合物的发展呈现出多元化的趋势 :茂络合物、非茂络合物以及茂非茂混合配体络合物 ,而其中茂、非茂混合配体络合物是近年来发展的一个新亮点 .关于茂钛族络合物、非茂钛族络合物近年已经有过许多的综述 ,而关于茂、非茂混合配体钛族络合物的综述却很少 .综述了近年来茂。

The progresses of group 4 complex exhibit multi-trends: Cp complex, non-Cp complex and complex with Cp and non-Cp mixed ligands. Among them, the complex with Cp and non-Cp mixed ligands is a new shining-point. In recent years, there are many reviews about Cp complex or non-Cp complex, but there is few review regarding the complex with Cp and non-Cp mixed ligands. This paper reviews the latest progress in the synthesis of group 4 complexes with Cp and non-Cp mixed ligands and their catalytic application for olefin polymerization.