摘要
用电化学方法研究NO气体同CoTPP、NiTPP、CuTPF、ZnTPP四种金属四苯基卟啉络合物作用的情况,用分子轨道进论解释可能的电化学活性中间态MTPP(NO)x的形成及所体现的循环伏安性质,实验表明,金属卟啉对NO的活化能力为ZnTPP>CoTPP>NiTPP>CuTPP。
An Electrochemistry study on interaction between nitric oxide and metallopor-phyrin Complexes (MTPP,M=Co,Ni,Cu,Zn) is presented. Molecular orbital theory was used to explain the formation of MTPP(NO)x and their cyclic voltammograms. In this expenriment, we found nitric oxide being actived in MTPP,and the activating ability of MTPP is ZnTPP>CoTPP>NiTPP> CuTPP.
出处
《厦门大学学报（自然科学版）》
CAS
CSCD
北大核心
1992年第6期665-667,共3页
Journal of Xiamen University：Natural Science
关键词
一氧化氮
金属卟啉
配位
活化
Nitiric oxide, Metalloporphyrin, Electrochemistry
