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全生物降解PLA/PBC薄膜的制备及性能研究 被引量:12

Preparation and Properties of Fully Biodegradable PLA/PBC Films
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摘要 以聚碳酸丁二醇酯(PBC)和聚乳酸(PLA)为主要原料,经双螺杆挤出机混合制得吹膜专用树脂,然后通过吹膜机制备出全生物降解PLA/PBC薄膜。采用材料试验机、差示扫描量热仪(DSC)、热重分析仪(TG)、酶降解性能和扫描电子显微镜(SEM)对全生物降解薄膜进行了分析。结果表明,全生物降解PLA/PBC材料具有很好的相容性,随着PBC含量的增加,全生物降解PLA/PBC薄膜的降解性能逐渐提高,薄膜具有良好的热稳定性,PBC含量为30份时,薄膜的断裂伸长率提高到192.50%。 Using twin-screw extruder,a blend was prepared by mixing polylactic acid(PLA) and poly(butylene carbonate)(PBC),blown into PLA/PBC biodegradable film by a film-blowing extruder.The properties of PLA/PBC biodegradable film was investigated by material testing machine,differential scanning calorimeter(DSC),thermo gravimetry(TG),enzyme degradation performance and scanning electron microscopy(SEM).The results indicated that the compatibility of the PLA/PBC biodegradable film was good.With the increasing of PBC content,the degradation of PLA/PBC biodegradable film improved gradually.The film had good thermal stability,and elongation at break of the film was 192.50%when the content of PBC was 30 phr.
出处 《中国塑料》 CAS CSCD 北大核心 2015年第2期49-52,共4页 China Plastics
基金 黑龙江省自然科学基金资助(E201259) 黑龙江省大学生创新创业训练计划项目(201410221045 201410221036)
关键词 聚乳酸 生物降解材料 聚碳酸丁二醇酯 韧性 降解性 薄膜 polylactic acid biodegradable material poly(butylene carbonate) toughness degradation property film
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参考文献5

  • 1宋亚男.聚乳酸基复合材料的性能与结构研究[D].大连理工大学2013
  • 2Wenxiang Zhu,Chuncheng Li,Dong Zhang,Guohu Guan,Yaonan Xiao,Liuchun Zheng.Thermal degradation mechanism of poly(butylene carbonate)[J]. Polymer Degradation and Stability . 2012 (9)
  • 3Wang, Jin,Zheng, Liuchun,Li, Chuncheng,Zhu, Wenxiang,Zhang, Dong,Guan, Guohu,Xiao, Yaonan.Synthesis and properties of biodegradable poly(ester-co-carbonate) multiblock copolymers comprising of poly(butylene succinate) and poly(butylene carbonate) by chain extension. Industrial and Engineering Chemistry . 2012
  • 4Zhu, Wenxiang,Huang, Xi,Li, Chuncheng,Xiao, Yaonan,Zhang, Dong,Guan, Guohu.High-molecular-weight aliphatic polycarbonates by melt polycondensation of dimethyl carbonate and aliphatic diols: Synthesis and characterization. Polymer International . 2011
  • 5Xiaohua Gu,Xue Song,Chenghua Shao et al.Electrospinning of Poly (butylene-carbonate):Effect of Solvents on the Properties of the Nanofibers Film. International Journal of Electrochemical Science . 2014

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