合成聚碳酸酯的新方法

A NEW PROCESS FOR THE SYNTHESIS OF POLYCARBONATE

介绍了CE公司新近披露的采用“环化”技术合成聚碳酸酯的新方法。对环状碳酸酯低聚物的合成方法、成环机理、成环条件和开环聚合方法以及新方法对改进和提高聚碳酸酯性能、开拓聚碳酸酯新品种的作用进行了阐述。

A new process for the synthesis of polycarbonate by cyclization technique, which was revealedby GE Co. recently, was introduced in this paper. The synthesis of the cyclic carbonate oligorner,the mechanism and condition of the cyclization, the process for ring opening polymerization, aswell as the effect of the new process on the improvement of the properties and the effect on thedevelopment of new grade of polycarbonate were described.