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五氯酚在沉积物中的吸附解吸迟滞行为 被引量:12

Hysteresis in the sorption and desorption of pentachlorophenol by sediments
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摘要 采用循环吸附 解吸实验法 ,研究了西湖、滇池、太湖、甬江和钱塘江表层沉积物对五氯酚的吸附特性 .结果表明五氯酚在 5种沉积物上均表现出解吸比吸附滞后的现象 .解吸迟滞系数表明 ,甬江沉积物的迟滞现象最明显 ,各沉积物的迟滞系数大小与沉积物中脂蜡占有机质总量的百分比成正相关 .研究认为 ,解吸迟滞行为主要是由沉积物中脂蜡组分对五氯酚的不可逆吸附造成的 .解吸迟滞现象的存在 。 The sorption/desorption behavior of pentachlorophenol(PCP) in five sediments were studied using multiple cycles of sorption/desorption experiments. The results showed that the five sediments were found to exhibit statistically significant sorption|desorption hysteresis. Correlations between the extent of hysteresis and the percentage of lipid in total organic matters indicated that lipid significantly affects this phenomenon. The hysteresis phenomenon was mostly caused by irreversible sorption of PCP on lipid in sediments. Because of hysteresis, the PCP ecotoxicity would be lower than expected.
出处 《环境科学学报》 CAS CSCD 北大核心 2004年第1期27-32,共6页 Acta Scientiae Circumstantiae
基金 杭州市环保局资助项目 (2 0 0 2 0 6 6 8)
关键词 五氯酚 沉积物 吸附 解吸 迟滞系数 不可逆吸附 湖泊 pentachlorophenol(PCP) sediment hysteresis index irreversible sorption
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  • 1张兵,郑明辉,刘芃岩,包志成,徐晓白.五氯酚在洞庭湖环境介质中的分布[J].中国环境科学,2001,21(2):165-167. 被引量:82
  • 2王子健,吕怡兵,王毅,马梅.淮河水体取代苯类污染及其生态风险[J].环境科学学报,2002,22(3):300-303. 被引量:50
  • 3Uhle M E, Chin Y P, Aiken G B, et al. Binding of polychlorinated biphenyls to aquatic humic substances: the role of substrate and sorbate properties on partitioning[J]. Environ Sci Technol, 1999, 33:2715-2718.
  • 4Park S S, Ersffeld K M. The effect of sediment organic carbon content on bioavailability of hydrophobic compounds in aquatic ecosystems[J]. Environmental Pollution, 1999, 105(1) : 9-15.
  • 5Chen W, Kan A T, Fu G, et al. Factors affecting the release of hydrophobic organic contaminants from natural sediments[J]. Environmental Toxicology and Chemistry, 2000, 19( 10): 2401-2408.
  • 6Bremle G, OIda L, Larsson P. Uptake of PCBs in fish in contaminated river systems: bioconeentration factors measured in field[J].Environ Sci Tachnol, 1995,29(10) :2010-2015.
  • 7Tang J, Carroquino M J, Robertson B K, et al. Combined effect of sequestration and bioremediation in reducing the bioavailability of polycyclic aromatic hydrocarbons in soil[J]. Environ Sci Technol, 1998, 32:3586-3690.
  • 8Pignatello J J, Xing B, Mechanisms of Slow Sorption of Organic Chemicals to Natural particles[J]. Environ Sci Technol, 1996,30(1):1-11.
  • 9Karapanagioti H K, Sabatini D A, Kleineidam S, et al. Phenanthrene sorption with heterogeneous organic matter in a landfill aquifer material[J]. Phys Chem Earth, 1999, 24(6) :535-541.
  • 10Kan A T, Fu G., Hunter M A, et al. Irreversible sorption of neutral hydrocarbons to sediments: experimental observatlons and model predictions[J ]. Environ Sci Technol, 1998,32 (7) : 892-902.

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