两个3,3′-偶氮联吡啶配合物的合成和性质的研究(英文)

Syntheses and properties of two 3,3′-azobispyridine complexes

合成了两个3,3′ 偶氮联吡啶配合物{[Cu(NO3)2(H2O)2(3,3′ azpy)2](1)和{[Mn(H2O)4(3,3′ azpy)](3,3′ azpy)3(PF6)2}n(2),并且用元素分析、红外和变温磁化率进行了表征.在75～300K的变温磁化率研究表明化合物(1)和(2)都遵守Curie Weiss定律.

The complexes{[Cu(NO 3) 2(H 2O) 2(3,3′ azpy) 2](1) and {[Mn(H 2O) 4(3,3′ azpy)](3,3′ azpy) 3(PF 6) 2} n (2) (3,3′ azpy = 3,3′ azobispyridine) were synthesized and characterized by elemental analyses, IR and Variable temperature magnetic susceptibility. Variable temperature magnetic susceptibility studies in the temperature range 75～300K, showed that the compounds (1) and (2) both obey the Curie Weiss law.