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尿素/添加剂湿法烟气同时脱硫脱氮研究(Ⅱ)——净化过程中SO_2和NO_x的吸收特性 被引量:27

Simultaneous Desulfurization and Denitrification from Flue Gas by Using Urea/Additive Solution (Ⅱ):Absorption Characteristics of SO_2 and NO_x in Cleaning Process
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摘要 简述了吸收过程传质理论———双膜理论的基本原理 ,据此研究了尿素/添加剂湿法烟气同时脱硫脱氮过程中SO2 和NOx 的吸收特性 .实验结果表明 ,在尿素/添加剂水溶液中 ,烟气中SO2 的吸收由气膜控制 ,是液相中伴有快速不可逆化学反应的气体吸收 ;NOx 的吸收由气膜和液膜共同控制 。 The basic principle of the two-membrane theory as the mass transfer th eory in absorption process was briefly stated. The principle was then used to in vestigate the absorption characteristics of SO 2 and NO x in the process o f simult aneous desulfurization and denitrification from flue gas using urea/additive sol ution. The experimental results show that, in urea/additive solution, the absorp tion process of SO 2 in flue gas going with quick irreversible chemical reactio ns is controlled by the gas membrane, while that of NO x going with slow irre versib le chemical reactions is controlled by both the gas membrane and the liquid memb rane.
出处 《华南理工大学学报(自然科学版)》 EI CAS CSCD 北大核心 2004年第2期14-17,共4页 Journal of South China University of Technology(Natural Science Edition)
基金 科技部 863计划项目 (2 0 0 2AA 52 9160 ) 广东省科技计划重大专项(A 3 0 40 2 0 3 ) 广东省环保局项目(2 0 0 1-3 4 )
关键词 尿素 添加剂 烟气 脱硫 脱氮 吸收特性 urea additive flue gas desulfurization denitrif ication absorption characteristic
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参考文献3

  • 1郝吉明.大气污染控制工程[M].高等教育出版社,1994..
  • 2Cabriele Centi, Nello Passarini. Combined DeSO2/DeNOx reduction on a copper on alumina sorbent-cata lyst I mechanism of SO2 oxidation-adsorption [J]. Industrial and Engineering Chemistry Research, 1992,31(8): 1947 - 1950.
  • 3Yeh J T. Integrated testing of the NOXSO processsimutaneous removal of SO2 and NOx from flue gas[J]. Chemical Engineering Communications, 1992,114:65-88.

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