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Formation Enthalpy Calculation of Oxygen Vacancy Defect in Doped Lithium Niobate Crystals

Formation Enthalpy Calculation of Oxygen Vacancy Defect in Doped Lithium Niobate Crystals
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摘要 The relationship between temperature and oxygen vacancy concentration is deduced in this paper. Based on the data of thermal weight-loss experiment, the formation enthalpies of congruent and several doped LN crystals have been calculated. It was found that the formation enthalpy of oxygen vacancies can be decreased evidently by doping valence-changeable ions. The experimental results were discussed and a new reduction process of the photorefractive LN crystal at a relatively low temperature was proposed, and the reduced crystals showed a good effect in practical use. The relationship between temperature and oxygen vacancy concentration is deduced in this paper. Based on the data of thermal weight-loss experiment, the formation enthalpies of congruent and several doped LN crystals have been calculated. It was found that the formation enthalpy of oxygen vacancies can be decreased evidently by doping valence-changeable ions. The experimental results were discussed and a new reduction process of the photorefractive LN crystal at a relatively low temperature was proposed, and the reduced crystals showed a good effect in practical use.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2004年第1期65-67,共3页 高等学校化学研究(英文版)
基金 SupportedbytheNationalNaturalScienceFoundationofChina(No .2 0 1710 15 )
关键词 Formation enthalpy calculation Oxygen vacancy defect Doped lithium niobate crystal Formation enthalpy calculation, Oxygen vacancy defect, Doped lithium niobate crystal
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参考文献6

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