具有好的溶解性和高的热稳定性的富勒烯-苝化合物的合成

Synthesis of A Novel Soluble and High Thermal Stable Fullerene-Perylene Dyad

在氩气保护下 ,利用 N- (正丁基 ) - N′- (4 -甲酰基苯氧戊基 ) - 1,6 ,7,12 -四 - (4 -叔丁基苯氧基 ) - 3,4 ,9,10 -⊥酰亚胺和 N-甲基甘氨酸产生的亚胺叶立德与富勒烯反应 ,合成了含富勒烯的⊥化合物 ,用 NMR、FT- IR、UV- Vis及 TGA等方法对其结构和性能进行了表征和测试。

A novel good soluble and high thermal stable fullerene-perylene dyad, in which a perylene moiety is attached to C 60, has been prepared by 1,3-dipolar cycloaddition of the azomethine ylides generated in situ from the aldehyde and N-methylglycine and characterized by NMR, FT-IR, TGA, UV-Vis absorption and fluorescent spectra etc.