后过渡金属催化降冰片烯加成聚合

The Vinyl Polymerization of Norbornene with Late Transition Metal Catalysts

综述了后过渡金属催化剂催化降冰片烯加成聚合的研究进展。主要介绍了Ni、Pd、Co三种金属催化剂各自的结构以及其催化降冰片烯聚合的特点 ,同时也阐述了Ni、Pd催化剂催化降冰片烯聚合的机理。

Advance in the vinyl polymerization of norbornene with late transition metal catalysts has been reviewed. In this paper, the structures of three kinds of late transition metal catalysts including Ni, Pd, Co and their characters of vinyl polymerization of norbornene have been introduced, and mechanism of vinyl polymerization of norbornene with Ni and Pd catalysts has been discussed.