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铍试剂Ⅲ为指示剂分光光度法测定盐中碘 被引量:3

Application of beryllium Ⅲ—photometric determinationof iodine in salt by color fading reaction
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摘要 It is found that in the medium of H2SO4,the fading reaction of Beryllium Ⅲ is accelerated by IO-3 with the KBr.The fading of the color intensity of Beryllium Ⅲ is found to be directly proportional to the amount of iodinate present.Based on these facts,a photometric method for the determination of iodine in salt was proposed.The decrease in absorbency(ΔA) was measured at the wavelength of 485 nm which is the absorption maximum of Beryllium Ⅲ.The detection limit is 1.47×10-8g/mL and the linear range is 0~12 μg/10 ml for iodine. It is found that in the medium of H_2SO_4,the fading reaction of Beryllium Ⅲ is accelerated by IO^-_3 with the KBr.The fading of the color intensity of Beryllium Ⅲ is found to be directly proportional to the amount of iodinate present.Based on these facts,a photometric method for the determination of iodine in salt was proposed.The decrease in absorbency(ΔA) was measured at the wavelength of 485 nm which is the absorption maximum of Beryllium Ⅲ.The detection limit is 1.47×10^(-8)g/mL and the linear range is 0~12 μg/10 ml for iodine.
作者 韩长秀
出处 《化学研究与应用》 CAS CSCD 北大核心 2004年第1期97-98,共2页 Chemical Research and Application
关键词 铍试剂Ⅲ 指示剂氧化褪色法 分光光度法 食盐 含量测定 photometry iodine iodinate Beryllium Ⅲ.
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