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The First Total Synthesis of 16-Hydroxygeranylgeraniol

The First Total Synthesis of 16-Hydroxygeranylgeraniol
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摘要 The facile synthesis of 16-hydroxygeranylgeraniol(1), a naturally existing alicyclic diterpene, by alkylation reaction of allylic iodide(3) with phenyl sulfone(4), is described. The facile synthesis of 16-hydroxygeranylgeraniol(1), a naturally existing alicyclic diterpene, by alkylation reaction of allylic iodide(3) with phenyl sulfone(4), is described.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2004年第1期40-41,共2页 高等学校化学研究(英文版)
基金 SupportedbytheNationalNaturalScienceFoundationofChina(No .2 0 0 72 0 12 )andtheSpecialResearchGrantforDoctoralSitesinChineseUniversities(No .2 0 0 10 730 0 0 1)
关键词 Total synthesis 16-Hydroxygeranylgeraniol Diterpene. Total synthesis, 16-Hydroxygeranylgeraniol, Diterpene.
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参考文献6

  • 1[1]Bohlmann F., Adler A., Jakupouic J., et al., Phytochemistry, 1982, 21, 1349
  • 2[2]Toyota M., Hostettmann K., Phytochemistry, 1990, 29, 1485
  • 3[3]Unbriet M., Sharpless K. B., J. Am. Chem. Soc., 1977, 99, 5526
  • 4[4]Marshall J. A., Andrews R. C., J. Org. Chem., 1985, 50, 1603
  • 5[5]Najera C., Yus M., Tetrahedron, 1999, 55, 10547
  • 6[6]Li S. H., Peng L. Z., Zhang T., et al., Chem. J. Chinese Universities, 2003, 24(5), 843

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