Thermal Stability and Luminescence Properties of Eu^(3+) and Tb^(3+) Complexes with a Silica Matrix by Sol-Gel Method 被引量：1

Thermal Stability and Luminescence Properties of Eu^(3+) and Tb^(3+) Complexes with a Silica Matrix by Sol-Gel Method

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摘要 Ternary complexes of europium and terbium with benzoic acid and 1, 10 phenanthroline [RE(BA) 3phen] (BA=benzoate phen=1,10 phenanthroline) were introduced into a silica matrix by sol gel method. The thermal stability and luminescence behavior of the complexes in silica gels were studied in comparison with the corresponding solid state complexes by thermal decomposition, excitation and emission spectra. The thermal stability of the complexes is enhanced in silica gel matrix and the luminescence remaines unchanged. Ternary complexes of europium and terbium with benzoic acid and 1, 10 phenanthroline [RE(BA) 3phen] (BA=benzoate phen=1,10 phenanthroline) were introduced into a silica matrix by sol gel method. The thermal stability and luminescence behavior of the complexes in silica gels were studied in comparison with the corresponding solid state complexes by thermal decomposition, excitation and emission spectra. The thermal stability of the complexes is enhanced in silica gel matrix and the luminescence remaines unchanged.

作者王淑萍王瑞芬张建军刘翠格

机构地区 Chemistry College Experimental Center

出处《Journal of Rare Earths》 SCIE EI CAS CSCD 2003年第2期153-156,共4页 稀土学报（英文版）

基金 ProjectsupportedbyNaturalScienceFoundationofHebeiProvince (2 0 2 14 0 2 0 3 14 8)

关键词 inorgamic chemistry sol gel rare earth complex benzoic acid 1 10 phenanthroline thermal stability LUMINESCENCE rare earths inorgamic chemistry sol gel rare earth complex benzoic acid 1,10 phenanthroline thermal stability luminescence rare earths

分类号 O614.33 [理学—无机化学] O641.4 [理学—物理化学]

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Journal of Rare Earths

2003年第2期

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Thermal Stability and Luminescence Properties of Eu^(3+) and Tb^(3+) Complexes with a Silica Matrix by Sol-Gel Method 被引量：1

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