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过渡金属离子调节的氮杂15-冠-5苯乙炔三联吡啶Pt(Ⅱ)络合物的最低激发态 被引量:2

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摘要 发展高选择性、高灵敏度的分子传感器是化学家们长期而艰巨的任务^[1-4].主体分子受到外界刺激(如与客体分子之间的相互作用)所产生的结构和性能的变化,继而将外界刺激转变为分子信息表达出来,从而实现对客体分子的识别.以有机小分子为发色团的主体分子已得到了广泛研究^[1,2]。
出处 《科学通报》 EI CAS CSCD 北大核心 2004年第3期293-295,共3页 Chinese Science Bulletin
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  • 1Métivier R Leray I Valeur B.A highly sensitive and selective fluorescent molecular sensor based on a calix[4]arene bearing four dansyl groups[J].Chem Commun,2003,:996-997.

同被引文献31

  • 1彭明丽,吴骊珠,张丽萍,佟振合.聚苯乙烯负载多吡啶铂(Ⅱ)炔基络合物的合成[J].感光科学与光化学,2004,22(5):321-326. 被引量:1
  • 2Lai S W, Lam H W, Lu W, et al. Observation of low-energy metal-metal-to-ligand eharge-transter absorption and emission : Electronic spectroscopy of cyclometalated platinum(Ⅱ) complexes with isocyanide ligands[J ]. Organometallics, 2002, 21, 226-234.
  • 3Aldridge T K, Stacy E M, McMillin D R. Studies of the room temperature absorption and emission spectra of [Pt(trpy)X]^+ systems[J]. Inorg. Chem., 1994, 33: 722-727.
  • 4Tears D K C, McMillin D R. Exciplex quenching of photoexcited platinum(Ⅱ) terpyridines: influence of the orbital parentage[J]. Coord. Chem. Rev., 2001, 211: 195-205.
  • 5FIissler M, McGarrah J E, Connick W B, et al. Platinum diirnine complexes: towards a molecular photochemical device[J]. Coord. Chem. Rev., 2000, 208: 115-137.
  • 6Lu W, Mi B X, Chan M C W, et al. Light-emitting tridentate cyclometalated platinum(Ⅱ) complexes containing α- alkynyl auxiliaries: tuning of photo- and electrophosphorescence[J]. J. Am. Chem. Soc. , 2004, 126: 4958.
  • 7Yam V W W, Tang R P L, Wong K M C. Synthesis, luminescence, electrochemistry, and ion-binding studies of platinum(Ⅱ) terpyridyl acetylide complexes[J]. Organometallic, 2001, 20: 4476.
  • 8Sun W F, Wu Z X, Yang Q Z, el al. Reverse saturable absorption of platinum ter/bipyridyl polyphenylacetylide complexes[J]. Appl. Phys. Lett., 2003, 86(2): 850.
  • 9Zhang D, Wu L Z, Zhou L, et al. Photocatalytic hydrogen production from hantzsch 1,4-dihydropyridines by platinum (Ⅱ) terpyridyl complexes in homogeneous solution[J]. J. Am. Chem. Soc. , 2004, 126: 3440-3441.
  • 10Zhang D, Wu L Z, Yang Q Z, et al. Versatile photosensitization system for ^1O2-mediated oxidation of alkenes based on nation-supported platinum (Ⅱ) Terpyridyl acetylide complex[J]. Org. Lett., 2003, 5(18): 3221-3224.

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