摘要
稀土三氟醋酸盐与双齿杂环胺形成的配合物报道不多。Heller在乙醇中合成了Nd(CF_3COO)_3Phen(Phen为邻菲罗啉)并用作激光材料;Singh等报道了在乙酸乙酯和苯溶剂中Ln(CF_3COO)_3(Pheh)的合成和性质;Zholl Jialie等报道了Ln(CF_3COO)
Five complexes of 1,10-phenanthroline with rare earth trifluoroacetate were prepared from water-organic solvents. The complexes have been characterized by elemental analysis, infrared spectra, UV spectra, conductivity measurements, X-ray powder patterns and thermal analysis and are found to have following constitution:Ln(CF_3COO)_3(Phen)_4·nH_2O(Ln=La、Pr, Nd, Sm, Er).
出处
《应用化学》
CAS
CSCD
北大核心
1992年第4期78-80,共3页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金
关键词
三氟醋酸
邻菲罗啉
络合物
稀土族
rare earth, trifluoroacetic acid, phenanthroline, complex, synthesis
